Transfer hydrogenation of cellulose to sugar alcohols over supported ruthenium catalysts

被引:155
作者
Kobayashi, Hirokazu [1 ]
Matsuhashi, Hisateru [1 ]
Komanoya, Tasuku [1 ,2 ]
Hara, Kenji [1 ]
Fukuoka, Atsushi [1 ]
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan
[2] Hokkaido Univ, Div Chem Sci & Engn, Grad Sch Chem Sci & Engn, Kita Ku, Sapporo, Hokkaido 0608628, Japan
关键词
CONVERSION; CARBON; HYDROLYSIS; SORBITOL;
D O I
10.1039/c0cc04311g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ru/C catalysts are active for the conversion of cellulose using 2-propanol or H-2 of 0.8 MPa as sources of hydrogen, whereas the Ru/Al2O3 catalyst is inactive in both reactions, indicating that the Ru/C catalysts are remarkably effective for the cellulose conversion.
引用
收藏
页码:2366 / 2368
页数:3
相关论文
共 18 条
[1]   Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].
Chheda, Juben N. ;
Huber, George W. ;
Dumesic, James A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183
[2]   Cooking cellulose in hot and compressed water [J].
Deguchi, Shigeru ;
Tsujii, Kaoru ;
Horikoshi, Koki .
CHEMICAL COMMUNICATIONS, 2006, (31) :3293-3295
[3]   Conversion of cellobiose into sorbitol in neutral water medium over carbon nanotube-supported ruthenium catalysts [J].
Deng, Weiping ;
Liu, Mi ;
Tan, Xuesong ;
Zhang, Qinghong ;
Wang, Ye .
JOURNAL OF CATALYSIS, 2010, 271 (01) :22-32
[4]   Conversion of Cellulose into Sorbitol over Carbon Nanotube-Supported Ruthenium Catalyst [J].
Deng, Weiping ;
Tan, Xuesong ;
Fang, Wenhao ;
Zhang, Qinghong ;
Wang, Ye .
CATALYSIS LETTERS, 2009, 133 (1-2) :167-174
[5]   Cellulose Conversion under Heterogeneous Catalysis [J].
Dhepe, Paresh L. ;
Fukuoka, Atsushi .
CHEMSUSCHEM, 2008, 1 (12) :969-975
[6]   Selective Transformation of Cellulose into Sorbitol by Using a Bifunctional Nickel Phosphide Catalyst [J].
Ding, Li-Ning ;
Wang, Ai-Qin ;
Zheng, Ming-Yuan ;
Zhang, Tao .
CHEMSUSCHEM, 2010, 3 (07) :818-821
[7]   Catalytic conversion of cellulose into sugar alcohols [J].
Fukuoka, Atsushi ;
Dhepe, Paresh L. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (31) :5161-5163
[8]   Direct Catalytic Conversion of Cellulose into Ethylene Glycol Using Nickel-Promoted Tungsten Carbide Catalysts [J].
Ji, Na ;
Zhang, Tao ;
Zheng, Mingyuan ;
Wang, Aiqin ;
Wang, Hui ;
Wang, Xiaodong ;
Chen, Jingguang G. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8510-8513
[9]   Non-catalyzed and Pt/γ-Al2O3-catalyzed hydrothermal cellulose dissolution-conversion: influence of the reaction parameters and analysis of the unreacted cellulose [J].
Jolle, Veronique ;
Chambon, Flora ;
Rataboul, Franck ;
Cabiac, Amandine ;
Pinel, Catherine ;
Guillon, Emmanuelle ;
Essayem, Nadine .
GREEN CHEMISTRY, 2009, 11 (12) :2052-2060
[10]   Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713