Catalytic conversion of cellulose into sugar alcohols

被引：677

作者：

Fukuoka, Atsushi ^{[1
]}

Dhepe, Paresh L. ^{[1
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 31期

关键词：

carbohydrates; catalysts; heterogeneous catalysis; reduction; water;

D O I：

10.1002/anie.200601921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sweetly done: Pt or Ru catalysts supported on inorganic oxides show high activity for the conversion of cellulose into sugar alcohols (mainly sorbitol) in water under hydrogen pressure; furthermore, the catalysts can be recycled over repeated runs. Glucose is produced in low yields, thus suggesting that the Pt (or Ru)/oxide works as a bifunctional catalyst for the hydrolysis of cellulose and subsequent reduction to sugar alcohols. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5161 / 5163

页数：3

共 20 条

[1] Biotechnology for the production of commodity chemicals from biomass
Danner, H
Braun, R
[J]. CHEMICAL SOCIETY REVIEWS, 1999, 28 (06) : 395 - 405
[2] Renewable hydrogen by aqueous-phase reforming of glucose
Davda, RR
Dumesic, JA
[J]. CHEMICAL COMMUNICATIONS, 2004, (01) : 36 - 37
[3] De Wulf P, 2000, BIOTECHNOL BIOENG, V69, P339, DOI 10.1002/1097-0290(20000805)69:3&lt
[4] 339::AID-BIT12&gt
[5] 3.0.CO
[6] 2-E
[7] Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas
Dhepe, PL
Ohashi, M
Inagaki, S
Ichikawa, M
Fukuoka, A
[J]. CATALYSIS LETTERS, 2005, 102 (3-4) : 163 - 169
[8] Fan L. T., 1987, CELLULOSE HYDROLYSIS, DOI DOI 10.1007/978-3-642-72575-3_4
[9] GLUCOSE HYDROGENATION ON PROMOTED RANEY-NICKEL CATALYSTS
GALLEZOT, P
CERINO, PJ
BLANC, B
FLECHE, G
FUERTES, P
[J]. JOURNAL OF CATALYSIS, 1994, 146 (01) : 93 - 102
[10] Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst
Hattori H.
Shishido T.
[J]. Catalysis Surveys from Asia, 1997, 1 (2) : 205 - 213

← 1 2 →