A remarkable water-soluble (molecular) alloy with two tuneable solid-to-solid phase transitions

被引：26

作者：

Braga, D

Cojazzi, G

Paolucci, D

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, CNR, Ctr Fis Macromol, I-40126 Bologna, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 09期

关键词：

D O I：

10.1039/b101749g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The organometallic cations [(eta (5)-C5H5)(2)Co](+) and [(eta (5)-C5H5)(2)Fe](+) are fully miscible in the solid state and form the mixed crystalline material [(eta (5)-C5H5)(2)CoxFe1-x][PF6], which undergoes two fully reversible phase transitions that can be tuned by varying the molar ratio of the two cations; the water-soluble organometallic salt thus possesses the behaviour of a molecular alloy.

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页码：803 / 804

页数：2

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