Red/near-infrared boron-dipyrromethene dyes as strongly emitting fluorophores

被引：58

作者：

Descalzo, Ana B. ^{[1
]}

Xu, Hai-Jun

Shen, Zhen

Rurack, Knut ^{[1
]}

机构：

[1] BAM Fed Inst Mat Res & Testing, Div I5, D-12489 Berlin, Germany

来源：

FLUORESCENCE METHODS AND APPLICATIONS: SPECTROSCOPY, IMAGING, AND PROBES | 2008年 / 1130卷

关键词：

BODIPY dyes; near-infrared fluorophores; fluorescent indicators; charge transfer; ring fusion;

D O I：

10.1196/annals.1430.016

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

We present an overview of the state of the art in long-wavelength boron-dipyrromethene (BODIPY) fluorophores, focusing on strategies to shift the absorption and emission bands into the red/near-infrared (NIR) range of the spectrum. This report also discusses chemical modifications of the chromophoric core to obtain analyte-responsive fluorophores, including examples of pH and metal ion indicators. Finally, we present a new series of phenanthrene-fused BODIPY dyes, emitting with high efficiency in the red/NIR region of the spectrum, as well as discussing potential applications thereof as probes.

引用

页码：164 / 171

页数：8

共 44 条

[1] Water soluble distyryl-boradiazaindacenes as efficient photosensitizers for photodynamic therapy [J].

Atilgan, Serdar ;

Ekmekci, Zeynep ;

Dogan, A. Lale ;

Guc, Dicle ;

Akkaya, Engin U. .

CHEMICAL COMMUNICATIONS, 2006, (42) :4398-4400

[2] Chiral discrimination with a fluorescent boron-dipyrromethene dye [J].

Beer, G ;

Rurack, K ;

Daub, J .

CHEMICAL COMMUNICATIONS, 2001, (12) :1138-1139

[3]

BISSELL RA, 1993, TOP CURR CHEM, V168, P223

[4] On the development of sensor molecules that display FeIII-amplified fluorescence [J].

Bricks, JL ;

Kovalchuk, A ;

Trieflinger, C ;

Nofz, M ;

Büschel, M ;

Tolmachev, AI ;

Daub, J ;

Rurack, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13522-13529

[5] 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes modified for extended conjugation and restricted bond rotations [J].

Chen, J ;

Burghart, A ;

Derecskei-Kovacs, A ;

Burgess, K .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (10) :2900-2906

[6] Effective PET and ICT switching of boradiazaindacene emission: A unimolecular, emission-mode, molecular half-subtractor with reconfigurable logic gates [J].

Coskun, A ;

Deniz, E ;

Akkaya, EU .

ORGANIC LETTERS, 2005, 7 (23) :5187-5189

[7] Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach [J].

Coskun, A ;

Akkaya, EU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) :10464-10465

[8] Bis(2-pyridyl)-substituted boratriazaindacene as an NIR-emitting chemosensor for Hg(II) [J].

Coskun, Ali ;

Yilmaz, M. Deniz ;

Akkaya, Engin U. .

ORGANIC LETTERS, 2007, 9 (04) :607-609

[9] Signal ratio amplification via modulation of resonance energy transfer: Proof of principle in an emission ratiometric Hg(II) sensor [J].

Coskun, Ali ;

Akkaya, Engin U. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) :14474-14475

[10]

DESCALZO AB, 2008, ORG LETT

← 1 2 3 4 5 →