Magnesium-catalyzed synthesis of organic carbonate from 1,2-diol/alcohol and carbon dioxide

被引：64

作者：

Du, Ya ^{[1
,2
]}

He, Liang-Nian ^{[1
,2
]}

Kong, De-Lin ^{[1
,2
]}

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 08期

基金：

中国国家自然科学基金;

关键词：

carbonylation; propylene glycol; propylene carbonate; magnesium; carbon dioxide;

D O I：

10.1016/j.catcom.2008.02.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low toxic magnesium and its oxide are proved to be a catalyst for highly selective synthesis of propylene carbonate (PC) through the carbonylation of propylene glycol (PG) with CO2 without any organic solvents or additives. Interestingly, the catalyst was demonstrated to be applicable to a variety of 1,2-diols such as glycol, phenyl glycol, and methanol, forming the corresponding carbonates in 100% selectivity. As a result, employing a low toxic and cheap catalyst could make PC synthesis much environmentally friendlier. A mechanistic insight into the Sn/Mg-catalyzed reaction of "PG + CO2" was also studied herein. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1754 / 1758

页数：5

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