Ruthenium-catalyzed oxidative cross-coupling of chelating arenes and cycloalkanes

被引:232
作者
Deng, Guojun [2 ]
Zhao, Liang [1 ]
Li, Chao-Jun [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
关键词
alkanes; arenes; C-C coupling; C-H activation; ruthenium;
D O I
10.1002/anie.200801544
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Alkane and arene join together: Various arenes were coupled directly with simple cycloalkanes. The reaction was catalyzed by ruthenium under oxidative conditions to give substituted cycloalkylarenes regioselectively (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6278 / 6282
页数:5
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