Copper catalyzed oxidative alkylation of sp3 C-H bond adjacent to a nitrogen atom using molecular oxygen in water

被引:246
作者
Basle, Olivier [1 ]
Li, Chao-Jun [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
关键词
D O I
10.1039/b707745a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and highly efficient C-C bond formation was developed by the activation of two sp(3) C-H.
引用
收藏
页码:1047 / 1050
页数:4
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共 41 条
  • [1] Direct monitoring of the asymmetric induction of solid-phase catalysis using circular dichroism:: Diamine-CuI-catalyzed asymmetric Henry reaction
    Arai, Takayoshi
    Watanabe, Masahiko
    Fujiwara, Akitsugu
    Yokoyama, Naota
    Yanagisawa, Akira
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) : 5978 - 5981
  • [2] Organocatalyzed solvent-free aza-Henry reaction:: A breakthrough in the one-pot synthesis of 1,2-diamines
    Bernardi, L
    Bonini, BF
    Capitò, E
    Dessole, G
    Comes-Franchini, M
    Fochi, M
    Ricci, A
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (23) : 8168 - 8171
  • [3] Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids:: Two distinct C-H activation pathways
    Chen, Xiao
    Goodhue, Charles E.
    Yu, Jin-Quan
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (39) : 12634 - 12635
  • [4] Zn(ODf)2:: preparation and application in asymmetric alkynylation of aldehydes
    Chen, ZL
    Xiong, WN
    Jiang, B
    [J]. CHEMICAL COMMUNICATIONS, 2002, (18) : 2098 - 2099
  • [5] Cross-coupling of sp3 C-H bonds and alkenes:: Catalytic cyclization of alkene-amide substrates
    DeBoef, B
    Pastine, SJ
    Sames, D
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (21) : 6556 - 6557
  • [6] Annulative tandem reactions based on Pd0/tBu3P-catalyzed cross-coupling and C(sp3)-H bond activation
    Dong, CG
    Hu, QS
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (14) : 2289 - 2292
  • [7] Doye S, 2001, ANGEW CHEM INT EDIT, V40, P3351, DOI 10.1002/1521-3773(20010917)40:18<3351::AID-ANIE3351>3.0.CO
  • [8] 2-B
  • [9] A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction
    Evans, DA
    Seidel, D
    Rueping, M
    Lam, HW
    Shaw, JT
    Downey, CW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (42) : 12692 - 12693
  • [10] The discovery of novel reactivity in the development of C-C bond-forming reactions:: In situ generation of zinc acetylides with ZnII/R3N
    Frantz, DE
    Fässler, R
    Tomooka, CS
    Carreira, EM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) : 373 - 381