Zinc(II)-operated intramolecular charge tranfer fluorescence emission in pyrene-2,2′-bipyridine conjugated molecular rods

被引:48
作者
Leroy, S [1 ]
Soujanya, T [1 ]
Fages, F [1 ]
机构
[1] Univ Bordeaux 1, UMR 5802, Chim Organ & Organomet Lab, F-33405 Talence, France
关键词
fluorescence; polycyclic aromatic compounds; complexation; electron transfer; molecular devices;
D O I
10.1016/S0040-4039(00)02338-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The design and synthesis of two conjugated pyrene-2,2'-bipyridine linear rods is described. Zn(II) ion complexation allows the formation of a highly polar emissive excited state through efficient photoinduced intramolecular charge transfer. (C) 2001 Elsevier Science Ltd. AII rights reserved.
引用
收藏
页码:1665 / 1667
页数:3
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