Analysis of the corrosion products on galvanized steels by FTIR spectroscopy

被引：22

作者：

Kasperek, J ^{[1
]}

Verchere, D

Jacquet, D

Phillips, N

机构：

[1] Univ Rouen, IUT, LASTSM, F-76821 Mt St Aignan, France

[2] IRSID, F-57214 Maizieres Metz, France

来源：

MATERIALS CHEMISTRY AND PHYSICS | 1998年 / 56卷 / 03期

关键词：

corrosion; Fourier transform infrared (FTIR) spectroscopy; galvanized steels;

D O I：

10.1016/S0254-0584(98)00167-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

FTIR reflectance spectroscopy has been used for the characterization of products formed by an accelerated wet ageing test on industrial hot-dip galvanized steel. Several aluminium contents are selected. Various products have been detected in this study. The kind and amount vary with the substrate, the type of ageing test used, the relative humidity level and the temperature. The galvanized coatings studied show a mixed zinc-aluminium compound, Zn6Al2(OH)(16)CO3. 4H(2)O. This phase is observed from the first exposure time on all coatings regardless of the amount of aluminium. Contrary to zinc, no basic aluminium compound has been detected. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：205 / 213

页数：9

共 32 条

[21]

PHILLIPS N, 1993, THESIS U PARIS

[22]

Ross S.D., 1972, Inorganic Infrared and Raman Spectra. McGraw-Hill European Chemistry Series

[23]

ROUQUEROL J, 1970, B SOC CHIM FR, V12, P423

[24]

SCHMIDT M, 1993, PHYS CHEM MINER, V20, P27

[25] SPECTROSCOPIC PROPERTIES OF SO4 (AND OH) IN DIFFERENT MOLECULAR AND CRYSTALLINE ENVIRONMENTS .1. INFRARED-SPECTRA OF CU4(OH)6SO4, CU4(OH)4OSO4, AND CU3(OH)4SO4 [J].

SECCO, EA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (02) :329-336

[26]

SKENAZI AF, 1985, P 14 INT GALV C MUN

[27] STUDY OF INFRARED VIBRATION MODES IN OXYHYDROXIDES OF ALUMINUM, BOEHMITE, AND DIASPORE [J].

STEGMANN, MC ;

VIVIEN, D ;

MAZIERES, C .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1973, A 29 (08) :1653-1663

[28]

STREZEL W, 1968, SPECTROCHIM ACTA A, V24, P353

[29] A LABORATORY STUDY OF THE EFFECT OF OZONE, NITROGEN-DIOXIDE, AND SULFUR-DIOXIDE ON THE ATMOSPHERIC CORROSION OF ZINC [J].

SVENSSON, JE ;

JOHANSSON, LG .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (08) :2210-2216

[30]

VANOOIJ WJ, 1988, POLYM MAT SCI ENG, V58, P22

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