Infrared spectroscopy of high k thin layer by multiple internal reflection and attenuated total reflection

被引:18
作者
Rochat, N [1 ]
Dabertrand, K [1 ]
Cosnier, V [1 ]
Zoll, S [1 ]
Besson, P [1 ]
Weber, U [1 ]
机构
[1] CEA Grenoble, DRT, DTS, LETI,SCPC, F-38054 Grenoble, France
来源
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 0, NO 8 | 2003年 / 0卷 / 08期
关键词
D O I
10.1002/pssc.200303858
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A complete analysis of HfO(2) high k thin layers deposited by metal organic chemical vapour deposition (MOCVD) is made by infrared spectroscopy using different optical configurations. Multiple internal reflection (MIR) and attenuated total reflection (ATR) are used, giving information about morphology and composition of the layers. Samples under investigation are HfO(2) layer of 3 to 12 nm thick deposited at 400 and 550degreesC on thin silicon oxide. MIR technique elucidates carbon content in the layer and ATR informs about the interface evolution, and the crystalline character of the HfO(2) layer. The high sensitivity of MIR coupled with the large spectral range available of ATR allow the full characterisation of these layers. (C) 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2961 / 2965
页数:5
相关论文
共 19 条
[1]  
COSNIER V, 2001, 01EX537 IWGI IEEE, P226
[2]   Passivation of an anodic oxide/p-Si interface stimulated by electron injection [J].
Dittrich, T ;
Burke, T ;
Koch, F ;
Rappich, J .
JOURNAL OF APPLIED PHYSICS, 2001, 89 (08) :4636-4642
[3]  
Harrick N.J., 1967, INTERNAL REFLECTION
[4]  
*JCPDS, 340104 JCPDS AM SOC
[5]   RELATION OF SI-H VIBRATIONAL FREQUENCIES TO SURFACE BONDING GEOMETRY [J].
LUCOVSKY, G .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1979, 16 (05) :1225-1228
[6]   INFRARED ABSORPTION STUDY OF METAL OXIDES IN THE LOW FREQUENCY REGION (700-240 CM1) [J].
MCDEVITT, NT ;
BAUN, WL .
SPECTROCHIMICA ACTA, 1964, 20 (05) :799-808
[7]  
Morstein M, 1999, CHEM VAPOR DEPOS, V5, P151, DOI 10.1002/(SICI)1521-3862(199908)5:4<151::AID-CVDE151>3.0.CO
[8]  
2-9
[9]  
Nakanishi K., 1977, INFRARED ABSORPTION
[10]   Multiple internal reflection spectroscopy: a sensitive non-destructive probe for interfaces and nanometric layers [J].
Olivier, M ;
Rochat, N ;
Chabli, A ;
Lefeuvre, G ;
Conne, F .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2001, 4 (1-3) :15-18