Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

被引:47
作者
Norikane, Yasuo [1 ]
Katoh, Ryuzi [2 ]
Tamaoki, Nobuyuki [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan
[2] Natl Inst Adv Ind Sci & Technol, Res Inst Instrumentat Frontier, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1039/b718813g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sterically hindered [ 0.0]( 3,3')-azobenzenophane exhibits thermal trans-to-cis isomerization to the thermodynamically stable cis-cis isomer, and reversible photochemical isomerization with good fatigue resistance.
引用
收藏
页码:1898 / 1900
页数:3
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