Polymeric tri-μ-oxo(pyrazine)molybdenum(VI)

被引：5

作者：

Liang, YC ^{[1
]}

Hong, MC ^{[1
]}

Cao, R ^{[1
]}

Sun, DF ^{[1
]}

Weng, JB ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2001年 / 57卷

关键词：

D O I：

10.1107/S160053680100441X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Mo2O6 (pz)](n) (pz is pyrazine, C4H4N2), was synthisized by hydrothermal reaction of MoO3, pyrazine-2-carboxylic acid and water at 443 K. The compound is a three-dimensional inorganic-organic hybrid polymer, in which pz acts as a bridging ligand. Each Mo atom is coordinated by five O atoms and one N atom in a distorted octahedral geometry, with the Mo-N distance being 2.449 (8) Angstrom and the Mo-O distances ranging from 1.682 (7) to 2.086 (8) Angstrom.

引用

页码：m159 / m161

页数：3