First emission studies of Tc2X82- systems (X = Cl, Br)

被引：8

作者：

Briggs, Breeze N. ^{[1
]}

McMillin, David R. ^{[1
]}

Todorova, Tanya K. ^{[2
]}

Gagliardi, Laura ^{[3
,4
]}

Poineau, Frederic ^{[5
]}

Czerwinski, Kenneth R. ^{[5
]}

Sattelberger, Alfred P. ^{[5
,6
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[2] Univ Geneva, Dept Phys Chem, CH-1211 Geneva, Switzerland

[3] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[4] Univ Minnesota, Inst Supercomp, Minneapolis, MN 55455 USA

[5] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

[6] Argonne Natl Lab, Energy Engn & Syst Anal Directorate, Argonne, IL 60439 USA

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 47期

基金：

美国国家科学基金会; 瑞士国家科学基金会;

关键词：

EXCITED-STATE; COMPLEXES; SPECTRA; LUMINESCENCE; TRANSITION; LIFETIMES; BOND;

D O I：

10.1039/c0dt00751j

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

The emission spectra of the solids [n-Bu4N](2)Tc2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the (1)delta-delta* excited state, as with the rhenium homologues, but has a shorter lifetime.

引用

页码：11322 / 11324

页数：3

共 21 条

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[2]

MONONUCLEAR + POLYNUCLEAR CHEMISTRY OF RHENIUM (3) - ITS PRONOUNCED HOMOPHILICITY [J].