Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

被引：145

作者：

Popov, Ilya ^{[1
]}

Lindeman, Sergey ^{[2
]}

Daugulis, Olafs ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

[2] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 24期

关键词：

C-H BONDS; COUPLING REACTIONS; TRIFLUOROMETHYLATION; PERFLUOROALKYL; COMPLEXES; CONVENIENT; REACTIVITY; STABILITY; CHEMISTRY; FLUORINE;

D O I：

10.1021/ja2041942

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP2Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.

引用

页码：9286 / 9289

页数：4

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