Thermosensitivity of aqueous solutions of poly(N,N-diethylacrylamide)

被引：319

作者：

Idziak, I ^{[1
]}

Avoce, D ^{[1
]}

Lessard, D ^{[1
]}

Gravel, D ^{[1
]}

Zhu, XX ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

MACROMOLECULES | 1999年 / 32卷 / 04期

关键词：

D O I：

10.1021/ma981171f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thermally induced phase separation of aqueous poly (N,N-diethylacrylamide) (PDEA) was studied by means of differential scanning calorimetry and US'-visible spectrophotometry. The polymer was shown to have a well-defined lower critical solution temperature (LCST) of 33 degrees C. The addition of sodium chloride to the polymer solution resulted in a linear decrease of the LCST, Sodium dodecyl sulfate, at concentrations up to its critical micelle concentration, caused a gradual increase in the LCST of PDEA.

引用

页码：1260 / 1263

页数：4

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