Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation

被引：98

作者：

Emmert, Marion H. ^{[1
]}

Gary, J. Brannon ^{[1
]}

Villalobos, Janette M. ^{[1
]}

Sanford, Melanie S. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 34期

关键词：

C-H activation; H/D exchange; ligand design; oxidation; platinum; C-H BONDS; POTASSIUM PEROXYDISULFATE; METAL-COMPLEXES; METHANE; ACTIVATION; ACETOXYLATION; CATALYTICA; CONVERSION; STABILITY; MECHANISM;

D O I：

10.1002/anie.201002351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic catalysts in HD: Palladium(II) and platinum(II) complexes of pyridinium-substituted bipyridine ligands are highly active and stable catalysts for H/D exchange and oxidation of aromatic C-H bonds (TONs up to 3200, TOFs up to 0.1 s-1; see scheme, EWC=electronwithdrawing group, EDC = electrondonating group). (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5884 / 5886

页数：3

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