C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium

被引：54

作者：

Ahlquist, Marten ^{[1
]}

Periana, Roy A. ^{[2
]}

Goddard, William A., III ^{[1
]}

机构：

[1] CALTECH, Mat & Proc Simulat Ctr MC 139 74, Pasadena, CA 91125 USA

[2] Scripps Res Inst, Jupiter, FL 33458 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 17期

关键词：

SUBSTITUTION-REACTIONS; METHANE; OXIDATION; CONVERSION; MECHANISM;

D O I：

10.1039/b821854d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt-II(bpym)Cl-2 (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

引用

页码：2373 / 2375

页数：3

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