A supramolecular assembly controlled by anions: threading and unthreading of a pseudorotaxane

被引：69

作者：

Montalti, M ^{[1
]}

Prodi, L ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802157k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pseudorotaxane formed in CH2Cl2 solution by (9-anthrylmethyl)methylammonium hexafluorophosphate salt and dibenzo-24-crown-8 can be unthreaded by addition of NBu4Cl through the formation of a strong ammonium chloride ion pair, while pseudorotaxane rethreading can be performed by addition of NHBu3PF6; all these processes can be followed by pronounced changes in the luminescence spectra, which could allow the use of this system as a fluorescent sensor for chloride ions.

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页码：1461 / 1462

页数：2

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