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Synthesis and structure of the new gallophosphate Mu-6 containing a gallium organic complex as part of the framework

被引：26
作者：
Reinert, P
Patarin, J
Marler, B
机构：
[1] Univ Haute Alsace, ENSCMU, Lab Mat Mineraux, UPRES A 7016, F-68093 Mulhouse, France
[2] Ruhr Univ Bochum, Inst Mineral, D-44780 Bochum, Germany
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1998年 / 35卷 / 4-5期
关键词：
D O I：
10.1016/S0992-4361(98)80434-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyclotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=1.7781(2)nm, c=1.5805(3)nm, beta= 92.05(3)degrees. The structure consists of gallophosphate chains of gallium-corner-sharing Ga2P2O4 four-rings. Each chain is connected to the others via a gallium-organic complex Lading to a three dimensional framework. This new gallophosphate shows low thermal stability, a complete amorphization being observed after calcination at 350 degrees C. The results of C-13 and P-31 solid state nmr spectroscopy are in agreement with the structure analysis.
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页码：389 / 403
页数：15
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