Chiral magnetic metal-organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

被引：138

作者：

Tong, Xiao-Lan ^{[1
,2
]}

Hu, Tong-Liang ^{[1
,2
]}

Zhao, Jiong-Peng ^{[1
,2
]}

Wang, Yue-Kui ^{[3
]}

Zhang, Hui ^{[4
]}

Bu, Xian-He ^{[1
,2
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, Tianjin Key Lab Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China

[3] Shanxi Univ, Inst Mol Sci, Taiyuan 030006, Peoples R China

[4] Xiamen Univ, Dept Chem, Xiamen 363105, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 45期

关键词：

COORDINATION POLYMERS; CRYSTAL-STRUCTURES; TOPOLOGY; CLUSTER; ARRAY;

D O I：

10.1039/c0cc03111a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.

引用

页码：8543 / 8545

页数：3

共 40 条

[1]

[Anonymous], 2000, Circular Dichroism: Principles and Applications

[2] Chemistry - Chirality, magnetism and light [J].

Barron, LD .

NATURE, 2000, 405 (6789) :895-896

[3]

Carlin R.L., 1977, MAGNETIC PROPERTIES

[4] Molecule-Based Magnetic Materials [J].

Coronado, E ;

Palacio, F ;

Veciana, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (23) :2570-2572

[5]

CRAIG DP, 1968, EXCITONS MOL CRYSTAL, P51

[6]

Davydov AS, 2008, UKR J PHYS, V53, P65

[7] Preparation of acentric porous coordination frameworks from an interpenetrated diamondoid array through anion-exchange procedures: Crystal structures and properties [J].

Du, M ;

Guo, YM ;

Chen, ST ;

Bu, XH ;

Batten, SR ;

Ribas, J ;

Kitagawa, S .

INORGANIC CHEMISTRY, 2004, 43 (04) :1287-1293

[8] First tetrameric NiII cluster with planar triangular topology exhibiting ferromagnetic pathways [J].

Du, M ;

Bu, XH ;

Guo, YM ;

Zhang, L ;

Liao, DZ ;

Ribas, J .

CHEMICAL COMMUNICATIONS, 2002, (14) :1478-1479

[9] Proton-controlled inter-conversion between an achiral discrete molecular square and a chiral interpenetrated double-chain architecture [J].

Du, M ;

Bu, XH ;

Guo, YM ;

Ribas, J ;

Diaz, C .

CHEMICAL COMMUNICATIONS, 2002, (21) :2550-2551

[10] Chiral, single-molecule nanomagnets:: synthesis, magnetic characterization and natural and magnetic circular dichroism [J].

Gerbier, P ;

Domingo, N ;

Gómez-Segura, J ;

Ruiz-Molina, D ;

Amabilino, DB ;

Tejada, J ;

Williamson, BE ;

Veciana, J .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (15) :2455-2460

← 1 2 3 4 →