State-to-state chemical reaction dynamics in polyatomic systems: Case studies

被引:29
作者
Valentini, JJ [1 ]
机构
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
关键词
chemical kinetics; hot atoms; hydrogen abstraction; collision complex; reaction cross section; energy disposal;
D O I
10.1146/annurev.physchem.52.1.15
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review illustrates the experimental study of chemical reaction dynamics using methods that select the quantum states and energy of the reactants and determine the quantum states and energy of the products. The focus is reaction dynamics in systems in which at least one of the reactants or products is a polyatomic molecule. The approach taken is to select four prototype reaction systems as case studies to demonstrate the detail of information and insight that can come from such experiments. Thus, the review is selective and neither claims nor attempts to be comprehensive. Reference to and discussion of theoretical reaction dynamics are included where computational results directly connect with the experiments.
引用
收藏
页码:15 / 39
页数:25
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