Synthesis and crystal structure of two new rare earth trimesate complexes:: ErTMA(H2O)5•3.5H2O and YTMA(H2O)6

被引：72

作者：

Daiguebonne, C

Guilloa, O ^{[1
]}

Gérault, Y

Lecerf, A

Boubekeur, K

机构：

[1] INSA, Lab Chim Mat Inorgan & Cristallog, F-35043 Rennes, France

[2] IMN, UMR 6502, F-44072 Nantes, France

来源：

INORGANICA CHIMICA ACTA | 1999年 / 284卷 / 01期

关键词：

crystal structures; rare earth complexes; trimesate complexes;

D O I：

10.1016/S0020-1693(98)00283-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two lanthanide complexes with trimesic acid have been obtained and structurally characterised. Er[C6H3(COO)(3)](H2O)(5). 3.5H(2)O crystallises in the monoclinic space group C2/c with unit cell dimensions of: a = 14.7396(15), b = 16.9874(15), c = 14.4591(14) Angstrom, beta = 118.754(9)degrees and Z = 8. Y[C6H3(COO)(3)](H2O)(6) crystallises in the monoclinic space group Cc with unit cell dimensions of: a = 11.373(2), b = 17.850(3), c = 7.134(1) Angstrom, beta = 119.14(3)degrees and Z = 4. Both structures consist of an extended network of metal ions coordinated by trimesate ions. The observations are analysed in terms of steric crowding about lanthanide atom using a cone-packing model. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：139 / 145

页数：7