Liquid-phase heterogeneous catalytic transfer hydrogenation of citral on basic catalysts

被引：45

作者：

Aramendía, MA ^{[1
]}

Borau, V ^{[1
]}

Jiménez, C ^{[1
]}

Marinas, JM ^{[1
]}

Ruiz, JR ^{[1
]}

Urbano, FJ ^{[1
]}

机构：

[1] Univ Cordoba, Dept Quim Organ, E-14004 Cordoba, Spain

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2001年 / 171卷 / 1-2期

关键词：

hydrogen transfer; citral; basic catalysts;

D O I：

10.1016/S1381-1169(01)00081-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The liquid-phase catalytic transfer hydrogenation of citral with 2-alkanols, 3-alkanols and cycloalkanols on basic catalysts obtained from Mg(OH)(2) and Ca(OH)(2) was studied. The catalysts were characterised by X-ray diffraction, and by adsorption of nitrogen and chemisorption of carbon dioxide. Both catalysts provided excellent results in terms of catalytic activity and selectivity in the reduction of citral with all the alcohols tested. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：153 / 158

页数：6

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