Palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates

被引：112

作者：

Chen, Ru ^{[1
]}

Liu, Saiwen ^{[1
]}

Liu, Xinhua ^{[1
]}

Yang, Luo ^{[1
]}

Deng, Guo-Jun ^{[1
]}

机构：

[1] Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Coll Chem, Xiangtan 411105, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 22期

基金：

中国国家自然科学基金;

关键词：

CROSS-COUPLING REACTIONS; BOND FUNCTIONALIZATION; SULFONYL CHLORIDES; ARENESULFONYL CHLORIDES; ARYL; ACTIVATION; HETEROCYCLES; ACIDS; HETEROARENES; OLEFINS;

D O I：

10.1039/c1ob06387a

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)center dot H2O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate to good yields.

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收藏

页码：7675 / 7679

页数：5

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