Relative configurations of carbapseudopentose moieties of hopanoids of the bacterium Zymomonas mobilis and the cyanobacterium 'Anacystis montana'

被引:23
作者
Herrmann, D
Bisseret, P
Connan, J
Rohmer, M
机构
[1] UNIV STRASBOURG 1,CNRS,INST LE BEL,F-67070 STRASBOURG,FRANCE
[2] ECOLE NATL SUPER CHIM,F-68093 MULHOUSE,FRANCE
[3] ELF AQUITAINE,F-64018 PAU,FRANCE
关键词
D O I
10.1016/0040-4039(96)00133-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A bacteriohopanetetrol cyclitol ether with a new configuration of its carbapseudopentose moiety has been isolated from the cyanobacterium 'Anacystis montana' and compared to a similar hopanoid previously isolated from Zymomonas mobilis. As shown by two dimensional H-1-NMR spectroscopy using Nuclear Overhauser Effect correlations, both compounds were diastereomers and differed from a third stereomer found in the biphytanyl lipids of the thermoacidophilic archaebacterium Sulfolobus sp.
引用
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页码:1791 / 1794
页数:4
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