Comparison of solvent-cast and hot-pressed P(EO)20LiN(SO2CF2CF3)2 polymer electrolytes containing nanosized SiO2

被引：46

作者：

Shin, JH ^{[1
]}

Alessandrini, F ^{[1
]}

Passerini, S ^{[1
]}

机构：

[1] IDROCOMB, Italian Agcy New Technol Energy & Environm, Hydrogen & Fuel Cell Project, I-00060 Rome, Italy

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2005年 / 152卷 / 02期

关键词：

D O I：

10.1149/1.1846713

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Solvent-cast and hot-pressed P(EO)(20)LiN(SO2CF2CF3)(2) (LiBETI) polymer electrolytes containing ceramic fillers such as 7 nm SiO2 and 2-4 mum gamma-LiAlO2 were prepared. The ionic conductivity and interfacial stability of these poly(ethylene oxide) electrolytes were investigated. The addition of ceramic fillers to solvent-cast and hot-pressed P(EO)(20)LiBETI polymer electrolytes did not result in any substantial improvement of ionic conductivity. However, solvent-cast SiO2-containing P(EO)(20)LiBETI polymer electrolytes showed a much higher interfacial resistance and Li stripping overvoltage than hot-pressed and filler-free solvent-cast electrolytes. (C) 2004 The Electrochemical Society. All rights reserved.

引用

收藏

页码：A283 / A288

页数：6

相关论文

共 29 条

[1] Poly(ethylene oxide)-LiN(SO2CF2CF3)2 polymer electrolytes -: II.: Characterization of the interface with lithium [J].

Appetecchi, GB ;

Passerini, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (07) :A891-A897

[2] PEO-LiN(SO2CF2CF3)2 polymer electrolytes -: I.: XRD, DSC, and ionic conductivity characterization [J].

Appetecchi, GB ;

Henderson, W ;

Villano, P ;

Berrettoni, M ;

Passerini, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (10) :A1171-A1178

[3] Hot-pressed, dry, composite, PEO-based electrolyte membranes I. Ionic conductivity characterization [J].

Appetecchi, GB ;

Croce, F ;

Hassoun, J ;

Scrosati, B ;

Salomon, M ;

Cassel, F .

JOURNAL OF POWER SOURCES, 2003, 114 (01) :105-112

[4] Composite polymer electrolytes with improved lithium metal electrode interfacial properties - I. Electrochemical properties of dry PEO-LiX systems [J].

Appetecchi, GB ;

Croce, F ;

Dautzenberg, G ;

Mastragostino, M ;

Ronci, F ;

Scrosati, B ;

Soavi, F ;

Zanelli, A ;

Alessandrini, F ;

Prosini, PP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4126-4132

[5] Ionic conductivity of plasticized (PEO)-LiCF3SO3 electrolytes [J].

Bandara, LRAK ;

Dissanayake, MAKL ;

Mellander, BE .

ELECTROCHIMICA ACTA, 1998, 43 (10-11) :1447-1451

[6] Conductivity in amorphous polyether nanocomposite materials [J].

Best, AS ;

Ferry, A ;

MacFarlane, DR ;

Forsyth, M .

SOLID STATE IONICS, 1999, 126 (3-4) :269-276

[7] ELECTROCHEMICAL PROPERTIES OF POLYETHYLENE OXIDE-LI[(CF3SO2)(2)N]-GAMMA-LIALO2 COMPOSITE POLYMER ELECTROLYTES [J].

BORGHINI, MC ;

MASTRAGOSTINO, M ;

PASSERINI, S ;

SCROSATI, B .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (07) :2118-2121

[8] Composite polymer electrolyte: the role of filler grain size [J].

Capiglia, C ;

Yang, J ;

Imanishi, N ;

Hirano, A ;

Takeda, Y ;

Yamamoto, O .

SOLID STATE IONICS, 2002, 154 :7-14

[9] Effects of nanoscale SiO2 on the thermal and transport properties of solvent-free, poly(ethylene oxide) (PEO)-based polymer electrolytes [J].

Capiglia, C ;

Mustarelli, P ;

Quartarone, E ;

Tomasi, C ;

Magistris, A .

SOLID STATE IONICS, 1999, 118 (1-2) :73-79

[10] Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes [J].

Croce, F ;

Persi, L ;

Scrosati, B ;

Serraino-Fiory, F ;

Plichta, E ;

Hendrickson, MA .

ELECTROCHIMICA ACTA, 2001, 46 (16) :2457-2461