Soluble transition-metal nanoparticles-catalysed hydrogenation of arenes

被引：106

作者：

Gual, Aitor ^{[1
]}

Godard, Cyril ^{[1
]}

Castillon, Sergio ^{[2
]}

Claver, Carmen ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Dept Quim Analit & Organ, Tarragona 43007, Spain

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 48期

关键词：

GAS-PHASE HYDROGENATION; NONAQUEOUS IONIC LIQUIDS; RHODIUM COLLOIDAL SUSPENSION; SELECTIVE HYDROGENATION; DIASTEREOSELECTIVE HYDROGENATION; RUTHENIUM NANOPARTICLES; O-XYLENE; METHYLATED CYCLODEXTRINS; HETEROGENEOUS CATALYSIS; CHEMOSELECTIVE HYDROGENATION;

D O I：

10.1039/c0dt00584c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Over the last decade, the hydrogenation of arenes catalysed by soluble nanoparticles has attracted much interest from both academic and industrial research groups due to the milder conditions and the interesting selectivities achieved when compared to those obtained with classical heterogeneous catalysts. When substituted arenes are used as substrates in this reaction, the stereoselectivity is a key objective, and high levels of enantioselectivity are yet to be achieved.

引用

页码：11499 / 11512

页数：14

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