Degradation of polyethylene designed for agricultural purposes

被引:70
作者
Feuilloley, P
César, G
Benguigui, L
Grohens, Y
Pillin, I
Bewa, H
Lefaux, S
Jamal, M
机构
[1] Univ Bretagne Sud, Lab Polymeres Proprietes Interfaces & Composites, F-56321 Lorient, France
[2] CEMAGREF, F-34033 Montpellier, France
[3] Stn Expt Horticole Bretagne Sud, F-56400 Auray, France
[4] Univ Maine, CNRS, UMR 6011, F-72085 Le Mans, France
[5] ADEME, F-49004 Angers, France
关键词
biodegradability; polyethylene; fragments; crosslinking;
D O I
10.1007/s10924-005-5529-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
For many years now, scientific articles have been published on the potential biodegradability of polyethylene. Polyethylene (PE) with peroxidant additives, in the form of agricultural films, is sold by various suppliers as biodegradable mulch. Even though, the photo-chemical and thermal degradation of these products under artificial laboratory conditions is highlighted, several extrapolation on the biodegradation and, moreover, on the neutral environmental impact of PE are made. In this study, three different commercial mulch films have been submitted to standardised biodegradation tests and the results are discussed. The first conclusions are that a very low degree of biodegradation of the commercial PE films is achieved from these tests and that crosslinked PE micro-fragments are found in soil after a very long period of time.
引用
收藏
页码:349 / 355
页数:7
相关论文
共 24 条
[1]   DEGRADATION PRODUCT PATTERN AND MORPHOLOGY CHANGES AS MEANS TO DIFFERENTIATE ABIOTICALLY AND BIOTICALLY AGED DEGRADABLE POLYETHYLENE [J].
ALBERTSSON, AC ;
BARENSTEDT, C ;
KARLSSON, S ;
LINDBERG, T .
POLYMER, 1995, 36 (16) :3075-3083
[2]   THE MECHANISM OF BIODEGRADATION OF POLYETHYLENE [J].
ALBERTSSON, AC ;
ANDERSSON, SO ;
KARLSSON, S .
POLYMER DEGRADATION AND STABILITY, 1987, 18 (01) :73-87
[3]   PHOTOOXIDATION AND BIODEGRADATION OF COMMERCIAL PHOTODEGRADABLE POLYETHYLENES [J].
ARNAUD, R ;
DABIN, P ;
LEMAIRE, J ;
ALMALAIKA, S ;
CHOHAN, S ;
COKER, M ;
SCOTT, G ;
FAUVE, A ;
MAAROUFI, A .
POLYMER DEGRADATION AND STABILITY, 1994, 46 (02) :211-224
[4]   Environmental biodegradation of polyethylene [J].
Bonhomme, S ;
Cuer, A ;
Delort, AM ;
Lemaire, J ;
Sancelme, M ;
Scott, G .
POLYMER DEGRADATION AND STABILITY, 2003, 81 (03) :441-452
[5]   Double stage oxidation of polyethylene as measured by chemiluminescence [J].
Broska, R ;
Rychly, J .
POLYMER DEGRADATION AND STABILITY, 2001, 72 (02) :271-278
[6]  
Chiellini E, 2002, 7 WORLD C BIOD POL P
[7]   In vivo UHMWPE biodegradation of retrieved prosthesis [J].
Costa, L ;
Luda, MP ;
Trossarelli, L ;
del Prever, EMB ;
Crova, M ;
Gallinaro, P .
BIOMATERIALS, 1998, 19 (15) :1371-1385
[8]   THE BIODEGRADATION OF POLYMERS - RECENT RESULTS [J].
DAVID, C ;
DEKESEL, C ;
LEFEBVRE, F ;
WEILAND, M .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1994, 216 :21-35
[9]   Unacceptable biodegradation of polyethylene in vivo [J].
delPrever, EB ;
Crova, M ;
Costa, L ;
Dallera, A ;
Camino, G ;
Gallinaro, P .
BIOMATERIALS, 1996, 17 (09) :873-878
[10]  
JAKUBOWICZ J, 1999, 2 INT C POL MOD STAB