Control of the coordination structure of organometallic palladium complexes in an apo-ferritin cage

被引：107

作者：

Abe, Satoshi ^{[1
]}

Niemeyer, Jochen ^{[4
]}

Abe, Mizue ^{[1
]}

Takezawa, Yusuke ^{[2
]}

Ueno, Takafumi ^{[1
,3
]}

Hikage, Tatsuo

Erker, Gerhard ^{[4
]}

Watanabe, Yoshihito ^{[2
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, High Intens Xray Diffract Lab, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Res Ctr Mat Sci, Nagoya, Aichi 4648602, Japan

[3] Japan Sci & Technol Agcy, PRESTO, Saitama 3320012, Japan

[4] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 32期

关键词：

D O I：

10.1021/ja802463a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the preparation of organometallic Pd(allyl) dinuclear complexes in protein cages of apo-Fr by reactions with [Pd(allyl)Cl](2) (allyl = eta(3)-C3H5). One of the dinuclear complexes is converted to a trinuclear complex by replacing a Pd-coordinated His residue to an Ala residue. These results suggest that multinuclear metal complexes with various coordination structures could be prepared by the deletion or introduction of His, Cys, and Glu at appropriate positions on protein surface.

引用

页码：10512 / +

页数：4

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