Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids

被引：23

作者：

Hemeon, I

Barnett, NW

Gathergood, N

Scammells, PJ

Singer, RD ^{[1
]}

机构：

[1] St Marys Univ, Dept Chem, Halifax, NS B3H 3C3, Canada

[2] Deakin Univ, Sch Biol & Chem Sci, Geelong, Vic 3217, Australia

[3] Monash Univ, Victorian Coll Pharm, Dept Med Chem, Melbourne, Vic 3052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2004年 / 57卷 / 02期

关键词：

D O I：

10.1071/CH03246

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids 1-butyl-3-methylimidazolium tetrafluoroborate [bmIm][BF4] and 1-butyl-3-methylimidazolium hexafluorophosphate [bmIm][PF6] were evaluated as reaction media for allylic and benzylic oxidation reactions using manganese dioxide. The use of ionic liquids as an extractant in the reaction work-up was also investigated. Procedures for recycling of the [bmIm][PF6] ionic liquids used in these MnO2 oxidation reactions were also developed.

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页码：125 / 128

页数：4

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