Bidentate lactate binding in aqueous solution in a cationic, heptadentate lanthanide complex: an effective chiral derivatising agent

被引：33

作者：

Dickins, RS ^{[1
]}

Love, CS ^{[1
]}

Puschmann, H ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 22期

关键词：

D O I：

10.1039/b106262j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structures of cationic, heptadentate lanthanide complexes of holmium and ytterbium bound to lactate are reported and the observed bidentate chelation in the solid state is consistent with near-IR CD (Yb) and solution NMR measurements; the complexes are shown to act as aqueous chiral derivatising agents for alpha -hydroxy acids.

引用

页码：2308 / 2309

页数：2

共 9 条

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