Experimental substantiation of the "Energy Landscape Concept" for solids: Synthesis of a new modification of LiBr

被引：52

作者：

Liebold-Ribeiro, Yvonne ^{[1
]}

Fischer, Dieter ^{[1
]}

Jansen, Martin ^{[1
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 23期

关键词：

atomic beam deposition; lithium bromide; polymorphism; solid-state structures;

D O I：

10.1002/anie.200800333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Global exploration of the energy landscape of lithium bromide led to the prediction of a new, metastable polymorph, β-LiBr (wurtzite structure type), which has now been synthesized (see E/V plot for comparison of polymorphs). Single-phase thick films of β-LiBr were obtained at -50°C and 2.3 × 10-4 mbar using the low-temperature-deposition technique. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4428 / 4431

页数：4

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