New polymeric sorbent for the solid-phase extraction of chlorophenols from water samples followed by gas chromatography-electron-capture detection

A polymeric material, polyaniline, was employed as a new sorbent for solid-phase extraction (SPE) of some environmental pollutants from water samples. Chlorophenols were extracted from aqueous samples by SPE using 120 mg polyaniline and determined by gas chromatography with electron-capture detection. The acetate esters of these phenols were formed by the direct addition of acetic anhydride to the organic extractant in the presence of K2CO3. Different conditions were applied to obtain higher retaining capacity and breakthrough volumes. The results compared with those obtained by other groups. The RSD for a river water sample spiked at sub-ppb level was lower than 10% (n=3) and detection limits were between 3 and 110 ng 1(-1). (C) 2001 Elsevier Science B.V. All rights reserved.