Silyl substitution as an aid in polymerization reactions: Oxidative coupling of silylthiophene, a route to highly conjugated polythiophene

被引：15

作者：

LerePorte, JP

Moreau, JJE

Sauvajol, JL

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,CNRS,LAB CHIM ORGANOMET,F-34053 MONTPELLIER 01,FRANCE

[2] UNIV MONTPELLIER 2,DYNAM PHASES CONDENSEES GRP,URA 233,F-34095 MONTPELLIER 05,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 521卷 / 1-2期

关键词：

silicon; polythiophene; oxidative coupling; silylthiophene; conducting polymer;

D O I：

10.1016/0022-328X(96)06327-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Raman spectroscopic and photoluminescence studies have shown that the oxidative polymerization of silyl thiophene monomers leads to highly conjugated polythiophene. Soluble high molecular weight polymers have been obtained by use of silylated monomers. The role of silicon is suggested to involve the stabilization of intermediate cationic species.

引用

页码：11 / 19

页数：9

共 41 条

[1] LIGHT-EMITTING-DIODES FABRICATED WITH CONJUGATED POLYMERS - RECENT PROGRESS [J].