Synthesis, characterization, and photoactivity of nanosized palladium clusters deposited on titania-modified mesoporous MCM-41

被引：24

作者：

Zheng, S ^{[1
]}

Gao, L ^{[1
]}

Zhang, QH ^{[1
]}

Sun, J ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2001年 / 162卷 / 01期

关键词：

D O I：

10.1006/jssc.2001.9373

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nanoparticles of Pd supported in the mesopores of titania-modified MCM-41 have been synthesized by the photodeposition method for the first time and characterized by XPS spectroscopy, N-2 sorption isotherms, XRD, TEM, SEM, diffusion reflectance UV-vis absorption spectra, and Raman spectra. The metallic Pd clusters were dispersed uniformly in the mesopores of titania-modified MCM-41. The photocatalytic activity of Pd-deposited titania-modified MCM-41 has been investigated. For the photoreduction of Cr(VI) to Cr(III), titania-modified MCM-41 exhibited much higher photocatalytic activity than the supports did. (C) 2001 Academic Press.

引用

页码：138 / 141

页数：4

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