Hydrothermal synthesis and characterization of nickel and cobalt sulfides nanocrystallines

被引：43

作者：

Liu, XH ^{[1
]}

机构：

[1] Cent S Univ, Dept Inorgan Mat, Changsha 410083, Hunan, Peoples R China

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2005年 / 119卷 / 01期

基金：

中国国家自然科学基金;

关键词：

hydrothermal; sea-urchinlike; alpha-NiS; beta-NiS; Co9S8; nanocrystalline;

D O I：

10.1016/j.mseb.2004.12.051

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Novel sea-urchinlike nanocrystallines of hexagonal alpha-NiS, rhombohedral beta-NiS, and cubic phase Co9S8 have been successfully synthesized via a facile hydrothermal synthetic route from the thiourea and hydrated metal chloride in hydrazine hydrate solution under mild conditions. The morphology and structure of the final products were investigated in detail by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and selected area electron diffraction (SAED). TEM and SEM show the formation process of the metal sulfides, and the probable formation mechanism of the sea-urchinlike nickel and cobalt. sulfides nanocrystallines was discussed on the basis of the experimental results. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：19 / 24

页数：6

共 27 条

[21]

NATH M, 2002, ANGEW CHEM, V114, P3601

[22] The preparation and phase transformation of nanocrystalline cobalt sulfides via a toluene thermal process [J].

Qian, XF ;

Zhang, XM ;

Wang, C ;

Xie, Y ;

Qian, YT .

INORGANIC CHEMISTRY, 1999, 38 (11) :2621-2623

[23] Coordination polymer route to wurtzite ZnS and CdS nanorods [J].

Qiao, ZP ;

Xie, G ;

Tao, J ;

Nie, ZY ;

Lin, YZ ;

Chen, XM .

JOURNAL OF SOLID STATE CHEMISTRY, 2002, 166 (01) :49-52

[24] PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS .20. SURFACE MODIFICATION AND STABILITY OF STRONG LUMINESCING CDS PARTICLES [J].

SPANHEL, L ;

HAASE, M ;

WELLER, H ;

HENGLEIN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5649-5655

[25] PREPARATION AND PROPERTIES OF MONODISPERSED SPHERICAL-COLLOIDAL PARTICLES OF ZINC-SULFIDE [J].

WILHELMY, DM ;

MATIJEVIC, E .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :563-570

[26] Characterization of ZnS nanoparticles prepared by new route [J].

Xu, JF ;

Ji, W .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1999, 18 (02) :115-117

[27] 3D silicon oxide nanostructures: from nanoflowers to radiolaria [J].

Zhu, YQ ;

Hsu, WK ;

Terrones, M ;

Grobert, N ;

Terrones, H ;

Hare, JP ;

Kroto, HW ;

Walton, DRM .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) :1859-1864

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