Phase equilibria and stability of the B2 phase in the Ni-Mn-Al and Co-Mn-Al systems

被引:40
作者
Kainuma, R [1 ]
Ise, M [1 ]
Ishikawa, K [1 ]
Ohnuma, I [1 ]
Ishida, K [1 ]
机构
[1] Tohoku Univ, Grad Sch Engn, Dept Mat Sci, Sendai, Miyagi 9808579, Japan
关键词
bcc aluminides; Ni-Al base alloy; Co-Al base alloy; order-disorder transition; B2; phase; phase equilibrium; miscibility gap;
D O I
10.1016/S0925-8388(98)00127-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The phase equilibria and ordering reactions in the composition region up to 50 at.% Al have been investigated in the Ni-Mn-Al and Co-Mn-Al systems at temperatures in the interval 850-1200 degrees C mainly by the diffusion couple method. The compositions of the gamma (Al: fcc-Ni, -Co, gamma-Mn), gamma' (Ll(2): Ni3Al), beta (B2: NiAl, CoAl, NiMn), beta-Mn (Al3: beta-Mn type), delta-Mn (A2: bcc-Mn) and epsilon (A3: hcp-(Mn, Al)) phases in equilibrium and the critical boundaries of the A2/B2 continuous ordering transition in the bcc phase region have been determined. It is shown that in the Mn-rich portion of the ternary systems both continuous and discontinuous A2 to B2 ordering transitions exist. The A2+B2 two-phase region in the isothermal sections has a lenticular shape and exists over a wide temperature range. The phase equilibria between the gamma, gamma', beta, beta-Mn, delta-Mn and epsilon phases are presented and the stability of the ordered bcc aluminides is discussed. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:173 / 180
页数:8
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