[HC{C(Me)NAr}(2)]Sn(OPri) (Ar = 2,6-(Pr2C6H3)-C-i) is shown to be an initiator for the living polymerisation of rac-lactide to heterotactic-enriched poly(lactide).
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Schmitt E., 1969, Patent, Patent No. [US3463158A, 3463158, 3,463,158]