Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

被引：16

作者：

Kadota, I

Park, CH

Sato, K

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Res Ctr Sustainable Mat Engn, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(01)01204-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：6195 / 6197

页数：3