Switchable-polarity solvents prepared with a single liquid component

被引：144

作者：

Phan, Lam ^{[1
]}

Andreatta, Jeremy R. ^{[2
]}

Horvey, Loel K. ^{[1
]}

Edie, Colin F. ^{[1
]}

Luco, Aimee-Lee ^{[1
]}

Mirchandani, Anish ^{[1
]}

Darensbourg, Donald J. ^{[2
]}

Jessop, Philip G. ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 01期

关键词：

D O I：

10.1021/jo7017697

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

[GRAPHICS] Known liquids that can reversibly switch their polarity at atmospheric pressure are all prepared as mixtures of two liquid components; we now report a series of switchable-polarity solvents that consist, in their low-polarity form, of only a single liquid component, a secondary amine. These solvents operate in a polarity range that is significantly lower than those of previously reported switchable solvents. Application to the separation and purification of a polymer and recovery of a catalyst is described.

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页码：127 / 132

页数：6

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