Studies of LiCoO2 coated with metal oxides

被引:129
作者
Chen, ZH [1 ]
Dahn, JR [1 ]
机构
[1] Dalhousie Univ, Dept Phys & Atmospher Sci, Halifax, NS B3H 3J5, Canada
关键词
D O I
10.1149/1.1611731
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
It has been reported that LiCoO2 coated with a metal oxide layer can deliver a capacity in excess of 140 mAh/g with improved capacity retention. Here, a commercial sample of LiCoO2 was coated with ZrO2, SiO2, and Al2O3 for comparative studies. Li/LiCoO2 cells using the coated LiCoO2 samples and a heat-treated control sample were charged and discharged between 3.6 and 4.5 V at a C/3 rate. All samples showed excellent capacity retention compared to the as-received commercial sample. Unlike literature reports, we find the capacity retention of coated LiCoO2 is independent of the specific oxide used for the coating. (C) 2003 The Electrochemical Society.
引用
收藏
页码:A221 / A224
页数:4
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