Extraction and separation studies of platinum(IV) with N-n-octylaniline

被引：50

作者：

Lokhande, TN ^{[1
]}

Anuse, MA ^{[1
]}

Chavan, MB ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Analyt Chem Lab, Kolhapur 416004, Maharashtra, India

来源：

TALANTA | 1998年 / 47卷 / 04期

关键词：

platinum(IV); N-n-octylaniline; solvent extraction;

D O I：

10.1016/S0039-9140(98)00172-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

N-n-octylaniline in xylene is used for the extractive separation of platinum(IV) from acidic media. Platinum(IV) was extracted quantitatively with 10 mi of 3% reagent in xylene from 0.5 to 10 and 2.5 to 10 M hydrochloric and sulphuric acid, respectively. It was stripped from organic phase with water and estimated photometrically with stannous chloride. The effect of metal ion, acids, reagent concentration and of various foreign ions has been investigated. The method affords binary separation of platinum(IV) from iron(III), cobalt(II), nickel(II) and copper(II), and is applicable to the analysis of synthetic mixtures and alloys. The method is fast, accurate and precise. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：823 / 832

页数：10

共 24 条

[1] Extraction of platinum(IV) from hydrochloric acid solutions by amine alamine 304 in xylene. Estimation of the interaction coefficient between PtCl62- and H+ [J].

Alguacil, FJ ;

Cobo, A ;

Coedo, AG ;

Dorado, MT ;

Sastre, A .

HYDROMETALLURGY, 1997, 44 (1-2) :203-212

[2]

[Anonymous], 1972, RECENT ADV ANAL CHEM

[3]

ANUSE MA, 1984, CHEM ANAL-WARSAW, V29, P409

[4] PYRIMIDINETHIOL AS A REAGENT FOR EXTRACTION SEPARATION OF PLATINUM METALS AND GOLD - DETERMINATION OF PD(II), OS(VIII) AND RU(III) [J].

ANUSE, MA ;

MOTE, NA ;

CHAVAN, MB .

TALANTA, 1983, 30 (05) :323-327

[5]

Beamish F.E., 1966, ANAL CHEM NOBLE META

[6]

Beamish F.E., 1977, ANAL NOBLE METALS OV

[7]

Gardlund ZG, 1973, LIQUID CRYSTALS ORDE, V2, P541, DOI 10.1007/978-1-4684-2727-1_48

[8] THE PREPARATION OF NORMAL-OCTYLANILINE AND ITS APPLICATION IN THE EXTRACTION OF NOBLE-METALS [J].

GEDYE, RN ;

BOZIC, J ;

DURBANO, PM ;

WILLIAMSON, B .

TALANTA, 1989, 36 (10) :1055-1058

[9]

JONES EA, 1973, 1569 NAT I MET

[10]

KADAMPATIL NB, 1992, B BISMUTH I, V64, P5

← 1 2 3 →