Ruthenium-mediated amidation of saturated C-H bonds and crystal structure of a bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane

被引：54

作者：

Au, SM ^{[1
]}

Zhang, SB ^{[1
]}

Fung, WH ^{[1
]}

Yu, WY ^{[1
]}

Che, CM ^{[1
]}

Cheung, KK ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a808048h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bis(tosyl)amidoruthenium(III) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane (Me(3)tacn) is prepared, and its crystal structure revealed the two tosylamido ligands in a cis configuration; the '[Ru-III(Me(3)tacn)(NHTs)(2)(OH)] + Ag(I) or PhINTs' protocol can effect amidation of saturated C-H bonds, and an electrophilic tosylimidoruthenium intermediate is implicated based on Hammett correlation studies and trapping experiments.

引用

页码：2677 / 2678

页数：2

共 19 条

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