A facile stereoselective synthesis of (Z,E)-2-silyl-substituted 1,3-dienes via palladium-catalyzed cross-coupling reaction

被引：7

作者：

Cai, MZ ^{[1
]}

Ye, XL

Wang, PP

机构：

[1] Jiangxi Normal Univ, Sch Chem & Chem Engn, Nanchang 330027, Peoples R China

[2] Jiujiang Coll, Dept Chem, Jiujiang 332000, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2005年 / 16期

关键词：

palladium catalysis; hydrozirconation; (E)-alpha-halovinylsilane; 1,3-diene; cross-coupling reaction; stereoselective synthesis;

D O I：

10.1055/s-2005-872174

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(E)-alpha-Halovinylsilanes undergo palladium-catalyzed cross-coupling reactions with (E)-alkenylzirconium complexes to afford stereoselectively (Z,E)-2-silyl-substituted 1,3-dienes in good yields.

引用

页码：2654 / 2656

页数：3

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