A copper(II) complex with rare μ1,1,1-azide ligand: Active catalyst for heterogeneous olefin epoxidation

被引：56

作者：

Roy, Partha ^{[1
]}

Dhara, Koushik ^{[1
]}

Manassero, Mario ^{[2
]}

Banerjee, Pradyot ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

[2] Univ Milan, Dipartimento Chim Struttura & Stereochim Inorgan, I-20133 Milan, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 03期

关键词：

Cu(II) complex; Azide; Heterogeneous catalysis; Olefin epoxidation;

D O I：

10.1016/j.inoche.2007.12.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(II) Complex [Cu2L(mu(1,1)-N-3)(mu(1,3)-N-3)(mu(1,1,1)-N-3)] (1) where HL = 4-methyl-2,6-bis(phenylmethyliminomethyl)phenol, with N2O donor ligand was synthesized and characterized by elemental analysis, FT-IR spectra and X-ray crystallography. X-ray crystallographic study reveals that it is a 1D chain along crystallographic b axis and the existence of rare mu(1,1,1)-azide bridging mode. The complex was immobilized on mesoporous silica and the immobilized compound was used as the active catalyst for the oxidation of olefins using tert-butyl hydroperoxide as oxidant. The results show that corresponding epoxides were produced in high yield with high selectivity. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：265 / 269

页数：5

共 32 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] Enzymatic activation of alkanes: constraints and prospective [J].

Ayala, M ;

Torres, E .

APPLIED CATALYSIS A-GENERAL, 2004, 272 (1-2) :1-13

[3] Comparison of liquid-phase olefin epoxidation over MoOx inserted within mesoporous silica (MCM-41, SBA-15) and grafted onto silica [J].

Bakala, PC ;

Briot, E ;

Salles, L ;

Brégeault, JM .

APPLIED CATALYSIS A-GENERAL, 2006, 300 (02) :91-99

[4] TITANIUM SILICATE MOLECULAR-SIEVE (TS-1)/H2O2 INDUCED TRIPHASE CATALYSIS IN THE OXIDATION OF HYDROPHOBIC ORGANIC-COMPOUNDS WITH SIGNIFICANT ENHANCEMENT OF ACTIVITY AND PARA-SELECTIVITY [J].

BHAUMIK, A ;

KUMAR, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (03) :349-350

[5] Silica-bound decatungstates as heterogeneous catalysts for H2O2 activation in selective sulfide oxidation [J].

Bigi, Franca ;

Corradini, Andrea ;

Quarantelli, Carla ;

Sartori, Giovanni .

JOURNAL OF CATALYSIS, 2007, 250 (02) :222-230

[6] Progress in enantioselective catalysis assessed from an industrial point of view [J].

Blaser, HU ;

Pugin, B ;

Spindler, F .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 231 (1-2) :1-20

[7] Nickel complexes with N2O donor ligands:: Syntheses, structures, catalysis and magnetic studies [J].

Chakraborty, Jishnunil ;

Nandi, Mahasweta ;

Mayer-Figge, Heike ;

Sheldrick, William S. ;

Sorace, Lorenzo ;

Bhaumik, Asim ;

Banerjee, Pradyot .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (32) :5033-5044

[8] Highly active 2D hexagonal mesoporous titanium silicate synthesized using a cationic-anionic mixed-surfactant assembly [J].

Chandra, Debraj ;

Bhaumik, Asim .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (14) :4879-4883

[9] Metal-triflate ionic liquid systems immobilized onto mesoporous MS41 materials as new and efficient catalysts for N-acylation [J].

Coman, Simona M. ;

Florea, Mihaela ;

Parvulescu, Vasile I. ;

David, Victor ;

Medvedovici, Andrei ;

De Vos, Dirk ;

Jacobs, Pierre A. ;

Poncelet, George ;

Grange, Paul .

JOURNAL OF CATALYSIS, 2007, 249 (02) :359-369

[10] Syntheses and X-ray structures of mixed-ligand salicylaldehyde complexes of Mn(III), Fe(III), and Cu(II) ions: Reactivity of the Mn(III) complex toward primary monoamines and catalytic epoxidation of olefins by the Cu(II) complex [J].

Das, G ;

Shukla, R ;

Mandal, S ;

Singh, R ;

Bharadwaj, PK ;

vanHall, J ;

Whitmire, KH .

INORGANIC CHEMISTRY, 1997, 36 (03) :323-329

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