Continuous flow synthesis of conjugated polymers

被引：47

作者：

Seyler, Helga ^{[1
]}

Jones, David J. ^{[1
]}

Holmes, Andrew B. ^{[1
]}

Wong, Wallace W. H. ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Inst Bio21, Parkville, Vic 3010, Australia

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 10期

基金：

澳大利亚研究理事会;

关键词：

HETEROJUNCTION SOLAR-CELLS; ORGANIC-SYNTHESIS; BANDGAP; EFFICIENCY; REACTORS; SUZUKI;

D O I：

10.1039/c1cc14315h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A selection of conjugated polymers, widely studied in organic electronics, was synthesised using continuous flow methodology. As a result of superior heat transfer and reagent control, excellent polymer molecular mass distributions were achieved in significantly reduced reaction times compared to conventional batch reactions.

引用

页码：1598 / 1600

页数：3

共 29 条

[1] New insights into the microstructure of GILCH-polymerized PPVs [J].

Becker, H ;

Spreitzer, H ;

Ibrom, K ;

Kreuder, W .

MACROMOLECULES, 1999, 32 (15) :4925-4932

[2]

Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO

[3]

2-N

[4] A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells [J].

Blouin, Nicolas ;

Michaud, Alexandre ;

Leclerc, Mario .

ADVANCED MATERIALS, 2007, 19 (17) :2295-+

[5] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[6]

Coffin RC, 2009, NAT CHEM, V1, P657, DOI [10.1038/NCHEM.403, 10.1038/nchem.403]

[7] Microreactors as tools for synthetic chemists -: The chemists' round-bottomed flask of the 21st century? [J].

Geyer, Karolin ;

Codee, Jeroen D. C. ;

Seeberger, Peter H. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (33) :8434-8442

[8] POLYMERIZATION OF ALPHA-HALOGENATED P-XYLENES WITH BASE [J].

GILCH, HG ;

WHEELWRIGHT, WL .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (6PA1) :1337-+

[9] Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices [J].

Grimsdale, Andrew C. ;

Chan, Khai Leok ;

Martin, Rainer E. ;

Jokisz, Pawel G. ;

Holmes, Andrew B. .

CHEMICAL REVIEWS, 2009, 109 (03) :897-1091

[10] Deciding Whether To Go with the Flow: Evaluating the Merits of Flow Reactors for Synthesis [J].

Hartman, Ryan L. ;

McMullen, Jonathan P. ;

Jensen, Klavs F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (33) :7502-7519

← 1 2 3 →