The chemistry of bridged borylene complexes

被引：78

作者：

Braunschweig, H ^{[1
]}

Colling, M ^{[1
]}

机构：

[1] Tech Hsch Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 614卷

关键词：

boron; iron; manganese; borylene complexes;

D O I：

10.1016/S0022-328X(00)00563-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stabilisation of borylenes (BX, X = various ligands) in the sphere of a transition metal was achieved for the first time in the case of bridged borylene complexes of the type [(LxM)(2)BX]. These compounds are characterised by 2c-2e bonds between metal and boron, thus belonging to the class of transition metal complexes of boron. Over the past 5 years different synthetic approaches were made, yielding the first structurally authentic metal complexes with a bridging EX ligand. Their synthesis, structure and reactivity is the subject of this paper. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：18 / 26

页数：9

共 61 条

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