Cascade complexation: a single cyano bridge links a pair of Cu(II) cations

被引：23

作者：

Bond, AD

Derossi, SA

Harding, CJ

McInnes, EJL

McKee, V

McKenzie, CJ

Nelson, J

Wolowska, J

机构：

[1] Univ So Denmark, Dept Chem, DK-5230 Odense, Denmark

[2] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England

[3] Univ Manchester, EPSRC Natl EPR Serv, Manchester M13 9PL, Lancs, England

[4] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

[5] Univ Ulster, Coleraine BT52 1SA, Londonderry, North Ireland

来源：

DALTON TRANSACTIONS | 2005年 / 14期

关键词：

D O I：

10.1039/b504916d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of structurally characterised mu-cyanodicopper(II) cryptates shows moderately strong antiferromagnetic interaction in the range -2J = 150-200 cm(-1), at the high end of the observed range for such assemblies. The lowest magnetic exchange coupling parameter is displayed where there is slight bending of the M-CN-M assembly, enforced by the constraints of cryptate encapsulation. Thermally accessible triplet EPR spectra are observed with zero-field splittings of the order of 0.13-0.14 cm(-1), confirming collinear ground-state d(z)(2) orbitals for Cu(II), consistent with their trigonal-bipyramidal coordination geometries.

引用

页码：2403 / 2409

页数：7

共 25 条

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HARDING CJ, UNPUB

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