Influence of polymerization temperature on molecular weight, photoluminescence, and electroluminescence for a phenyl-substituted poly(p-phenylenevinylene)

被引：34

作者：

Johansson, DM

Theander, M

Srdanov, G

Yu, G

Inganäs, O

Andersson, MR ^{[1
]}

机构：

[1] Chalmers Univ Technol, Dept Polymer Technol, SE-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Dept Organ Chem, SE-41296 Gothenburg, Sweden

[3] Linkoping Univ, Dept Phys IFM, SE-58183 Linkoping, Sweden

[4] UNIAX Corp, Goleta, CA 93117 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 11期

关键词：

D O I：

10.1021/ma001921x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present the synthesis and characterization of poly(2-(2",5'-bis(2"-ethylhexyloxy)phenyl)-1,4-phenylenevinylene) (BEHP-PPV) polymerized at different temperatures. The photoluminescence efficiencies in the solid state of BEHP-PPV obtained at 144 and 0 degreesC are 28% and 60%, respectively. H-1 NMR measurements showed a lower concentration of structural defects for BEHP-PPV obtained at lower temperatures, which can explain the increased photoluminescence efficiencies for these polymers. Polymerization temperatures below 0 degreesC decrease the molecular weight without changing the photoluminescence efficiency to any large extent. The electroluminescence efficiencies follow the trend in the photoluminescence efficiencies.

引用

页码：3716 / 3719

页数：4

共 17 条

[11] Synthesis and characterization of highly soluble phenyl-substituted poly(p-phenylenevinylenes) [J].