Translational and rotational diffusions of multiwalled carbon nanotubes with static bending

被引:22
作者
Lee, Heon Sang [1 ]
Yun, Chang Hun [1 ]
机构
[1] LG Chem Ltd, Ctr Technol, Taejon 305343, South Korea
关键词
D O I
10.1021/jp803363j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that apparent persistence lengths of multiwalled carbon nanotubes decrease drastically to hundreds of nanometers if and only if they have static bend points. We find that the apparent persistence length of multiwalled carbon nanotubes with static bend points is also proportional to the reciprocal temperature such as the purely elastic worm-like chain around room temperature. Our results demonstrated that the mobility of multiwalled carbon naDotubes with static bend points must be enhanced by thermal fluctuation even at lowtemperature ranges from 278 to 363 K. We anticipate our paper to be a starting point for more sophisticated statistical mechanics models for the quantitative shape factor and the mobility of carbon naDotubes.
引用
收藏
页码:10653 / 10658
页数:6
相关论文
共 22 条
[21]   Particle pressure in sheared Brownian suspensions [J].
Yurkovetsky, Yevgeny ;
Morris, Jeffrey F. .
JOURNAL OF RHEOLOGY, 2008, 52 (01) :141-164
[22]   Small angle neutron scattering from single-wall carbon nanotube suspensions: evidence for isolated rigid rods and rod networks [J].
Zhou, W ;
Islam, MF ;
Wang, H ;
Ho, DL ;
Yodh, AG ;
Winey, KI ;
Fischer, JE .
CHEMICAL PHYSICS LETTERS, 2004, 384 (1-3) :185-189